Issue 86, 2021

Accessing three oxidation states of cobalt in M6L3 nanoprisms with cobalt–porphyrin walls

Abstract

Nanocages with porphyrin walls are common, but studies of such structures hosting redox-active metals are rare. Pt2+-linked M6L3 nanoprisms with cobalt–porphyrin walls were prepared and their redox properties were evaluated electrochemically and chemically, leading to the first time that cobalt–porphyrin nanocages have been characterized in CoI, CoII, and CoIII states.

Graphical abstract: Accessing three oxidation states of cobalt in M6L3 nanoprisms with cobalt–porphyrin walls

Supplementary files

Article information

Article type
Communication
Submitted
31 Aug. 2021
Accepted
06 Okt. 2021
First published
06 Okt. 2021

Chem. Commun., 2021,57, 11342-11345

Accessing three oxidation states of cobalt in M6L3 nanoprisms with cobalt–porphyrin walls

P. T. Blackburn, I. F. Mansoor, K. G. Dutton, A. M. Tyryshkin and M. C. Lipke, Chem. Commun., 2021, 57, 11342 DOI: 10.1039/D1CC04860K

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