Issue 70, 2021

Hydrogen bonding-catalysed alcoholysis of propylene oxide at room temperature

Abstract

Alcoholysis of propylene oxide (PO) is achieved over azolate ionic liquids (IL, e.g., 1-hydroxyethyl-3-methyl imidazolium imidazolate) at room temperature, accessing glycol ethers in high yields with excellent selectivity (e.g., >99%). Mechanism investigation indicates that cooperation of hydrogen-bonding of the anion with methanol and that of the cation with PO catalyses the reaction.

Graphical abstract: Hydrogen bonding-catalysed alcoholysis of propylene oxide at room temperature

Supplementary files

Article information

Article type
Communication
Submitted
05 Jūl. 2021
Accepted
30 Jūl. 2021
First published
10 Aug. 2021

Chem. Commun., 2021,57, 8734-8737

Hydrogen bonding-catalysed alcoholysis of propylene oxide at room temperature

Y. Xu, Y. Zhao, F. Zhang, Y. Wang, R. Li, J. Xiang and Z. Liu, Chem. Commun., 2021, 57, 8734 DOI: 10.1039/D1CC03602E

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