Issue 71, 2021

Aerobic oxidation and oxidative esterification of alcohols through cooperative catalysis under metal-free conditions

Abstract

The ABNO@PMO-IL-Br material obtained by anchoring 9-azabicyclo[3.3.1]nonane-3-one N-oxyl (keto-ABNO) within the mesopores of periodic mesoporous organosilica with bridged imidazolium groups is a robust bifunctional catalyst for the metal-free aerobic oxidation of numerous primary and secondary alcohols under oxygen balloon reaction conditions. The catalyst, furthermore, can be successfully employed in the first metal-free self-esterification of primary aliphatic alcohols affording valued esters.

Graphical abstract: Aerobic oxidation and oxidative esterification of alcohols through cooperative catalysis under metal-free conditions

Supplementary files

Article information

Article type
Communication
Submitted
05 Jūn. 2021
Accepted
09 Aug. 2021
First published
09 Aug. 2021
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2021,57, 8897-8900

Aerobic oxidation and oxidative esterification of alcohols through cooperative catalysis under metal-free conditions

B. Karimi, M. Ghahremani, H. Vali, R. Ciriminna and M. Pagliaro, Chem. Commun., 2021, 57, 8897 DOI: 10.1039/D1CC02937A

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