Issue 41, 2020

Self-healable transparent polymer/salt hybrid adhesive via a ternary bonding effect

Abstract

Tremendous attention has been focused on the design and fabrication of intrinsic self-healing materials in recent years; however, the fabrication of self-healing materials with high transparency and high adhesion strength is still a challenge. Here, we develop a novel transparent self-healing adhesive with multiple functions by simply blending poly(2-ethyl-2-oxazoline) (PEOZ), poly(4-hydroxy styrene) (PHS), and CaCl2, and discover that the anion Cl also plays a significant role in accelerating the self-healing process by anion–ligand coordination in the form of hydrogen bonding, which has been seriously neglected in previous work. Unlike the common single metal–ligand coordination approach, the enhancement of self-healing results from novel co-existing ternary bridging bonds: metal–ligand coordination, ionic bond, and anion coordination. The universality of the new concept has been verified with other typical soluble salts MgCl2, NaCl, and Ca(NO3)2, providing a new dimension in the comprehension of the self-healing mechanisms. As a result, the hybrid shows outstanding multifunctional performance compared with the most recently published self-healable adhesives taking into consideration the transparency (T550 = 98.9%), adhesion strength (2.57 MPa), and self-healing efficiency (91%), enabling its application as an optical material, an adhesive and also a conservation material for cultural heritage.

Graphical abstract: Self-healable transparent polymer/salt hybrid adhesive via a ternary bonding effect

Supplementary files

Article information

Article type
Paper
Submitted
16 Jūl. 2020
Accepted
30 Sept. 2020
First published
30 Sept. 2020

J. Mater. Chem. A, 2020,8, 21812-21823

Self-healable transparent polymer/salt hybrid adhesive via a ternary bonding effect

Y. Zhang, K. Zhang, X. Li, T. Li, Q. Ye, L. Tan and B. Wei, J. Mater. Chem. A, 2020, 8, 21812 DOI: 10.1039/D0TA06935C

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