Issue 23, 2020

High and reversible SO2 capture by a chemically stable Cr(iii)-based MOF

Abstract

Partially fluorinated MIL-101(Cr) shows high SO2 capture (up to 18.4 mmol g−1 at 298 K and up to 1 bar), chemical stability towards dry and humid SO2 and an outstanding cycling performance with facile regeneration. In situ DRIFT spectroscopy demonstrated the preferential adsorption sites within MIL-101(Cr)-4F(1%).

Graphical abstract: High and reversible SO2 capture by a chemically stable Cr(iii)-based MOF

Supplementary files

Article information

Article type
Communication
Submitted
10 Dec. 2019
Accepted
09 Apr. 2020
First published
10 Apr. 2020

J. Mater. Chem. A, 2020,8, 11515-11520

High and reversible SO2 capture by a chemically stable Cr(III)-based MOF

E. Martínez-Ahumada, M. L. Díaz-Ramírez, H. A. Lara-García, D. R. Williams, V. Martis, V. Jancik, E. Lima and I. A. Ibarra, J. Mater. Chem. A, 2020, 8, 11515 DOI: 10.1039/C9TA13524C

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