Issue 72, 2020

Recent advances in graphene-based materials for dye-sensitized solar cell fabrication

Abstract

In the past few years, dye-sensitized solar cells (DSSCs) have received considerable research attention, as potential alternatives to the commonly used, but expensive, silicon-based solar cells owing to the low-cost, facile fabrication procedures, less impact on the environment, capability of working even under low incoming light levels, and flexibility of DSSCs. However, the relatively low power conversion efficiencies (PCEs) and poor long-term operational stability of DSSCs still limit their large-scale and commercial applications. As a consequence, this has prompted tremendous research effort towards the realization of high performance and sustainable devices, through tailoring of the properties of the various DSSC components, via approaches such as introducing novel materials and new synthesis techniques. Among these, the application of novel materials, especially carbon-based materials, such as graphene and its derivatives, is more appealing due to their excellent optoelectronic, mechanical, thermal and chemical properties, which give them ample potential to replace or modify the traditional materials that are commonly used in the fabrication of the various DSSC components. In addition, the low-cost, abundance, non-toxicity, large specific surface area, flexibility and superior stability of graphene-based materials have enabled their recent use as photoanodes, i.e., transparent conducting electrodes, semiconducting layers and dye-sensitizers, electrolytes and counter electrodes in DSSCs. Recently, the introduction of graphene-based materials into DSSCs resulted in a pronounced increase in PCE from ∼0.13 to above 12.00%. Thus, employing the recent breakthroughs can further improve the optoelectronic properties of the various DSSC components and, hence, close the gap between DSSCs and their silicon-based counterparts that are currently exhibiting desirable PCEs of above 26%. Therefore, this review focuses on the recent applications of graphene-based materials as photoanodes, electrolytes and counter electrodes, for the possible fabrication of all-carbon-based DSSCs. The limitations, merits and future prospects of graphene-based DSSCs are discussed, so as to improve their photovoltaic performance, sustainability and cost-effectiveness.

Graphical abstract: Recent advances in graphene-based materials for dye-sensitized solar cell fabrication

Article information

Article type
Review Article
Submitted
17 Okt. 2020
Accepted
26 Nov. 2020
First published
16 Dec. 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 44453-44469

Recent advances in graphene-based materials for dye-sensitized solar cell fabrication

E. Muchuweni, B. S. Martincigh and V. O. Nyamori, RSC Adv., 2020, 10, 44453 DOI: 10.1039/D0RA08851J

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements