Issue 3, 2020

A direct Z-scheme Bi2WO6/NH2-UiO-66 nanocomposite as an efficient visible-light-driven photocatalyst for NO removal

Abstract

To explore an efficient photocatalyst for NO pollution, a direct Z-scheme photocatalytic system is successfully fabricated by coupling Bi2WO6 with NH2-UiO-66 via a simple hydrothermal synthesis technique. The Z-scheme system promotes the NO photocatalytic oxidation activity with an optimum NO removal rate of 79%, which is 2.7 and 1.2 times that obtained by using only pristine Bi2WO6 and NH2-UiO-66, respectively. Simultaneously, superior selectivity for converting NO to NO3/NO2 is observed. The enhanced photocatalytic performance of the Bi2WO6/NH2-UiO-66 hybrids is attributed to the following two aspects: (i) large specific area of NH2-UiO-66, which exposes more active sites and is beneficial to the adsorption and activation of NO; (ii) outstanding Z-scheme structure constructed between BiWO6 and NH2-UiO-66, which can improve the efficiency of the separation of electron–hole pairs and preserves the strong oxidation ability of hybrids. ESR analysis shows that ·O2 and ·OH contribute to NO removal. A possible photocatalytic mechanism of NO oxidation on the direct Z-scheme photocatalyst (BWO/2NU) under visible light irradiation is proposed. This work displays the BWO/2NU hybrid's potential for treating low-concentration air pollutants, and the proposed Z-scheme photocatalyst design and promotion mechanism may inspire more rational synthesis of highly efficient photocatalysts for NO removal.

Graphical abstract: A direct Z-scheme Bi2WO6/NH2-UiO-66 nanocomposite as an efficient visible-light-driven photocatalyst for NO removal

Supplementary files

Article information

Article type
Paper
Submitted
08 Nov. 2019
Accepted
23 Dec. 2019
First published
08 Janv. 2020
This article is Open Access
Creative Commons BY-NC license

RSC Adv., 2020,10, 1757-1768

A direct Z-scheme Bi2WO6/NH2-UiO-66 nanocomposite as an efficient visible-light-driven photocatalyst for NO removal

Y. Liu, Y. Zhou, Q. Tang, Q. Li, S. Chen, Z. Sun and H. Wang, RSC Adv., 2020, 10, 1757 DOI: 10.1039/C9RA09270F

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements