Issue 9, 2020

Oxidative ionothermal synthesis for micro and macro Zn-based materials

Abstract

Zinc oxide (ZnO) is a multifunctional nanomaterial with a wide range of applications ranging from biosensors to solar cells. It is mainly mass-produced by air-oxidising vaporised metallic zinc at high temperatures without good particle uniformity. In a quest for environmentally-benign, cost-effective and high particle uniformity fabrication methods, many strategies had been proposed. However, recent methods utilise Zn salts as starting materials, produced commercially from metallic zinc, instead of the metallic Zn itself. We demonstrate that ZnO nano–macro particles (e.g. nanorods, needles and hierarchical structures) and other compounds [Zn(OH)2, Zn5(OH)8Cl2 or Zn5(OH)6(CO3)2] form spontaneously by direct oxidation of metallic zinc in aqueous ionic liquids (1-butyl-3-methylimidazolium chloride). Further, their chemical structure and morphology can be controlled by adjusting the concentration, temperature and exposure time. The environmentally benign and tunable nature of this novel oxidative ionothermal synthesis offers potential for new avenues towards application-motivated tailoring of ZnO and other nano and macro materials fabrication.

Graphical abstract: Oxidative ionothermal synthesis for micro and macro Zn-based materials

Supplementary files

Article information

Article type
Paper
Submitted
31 Aug. 2020
Accepted
13 Nov. 2020
First published
13 Nov. 2020
This article is Open Access
Creative Commons BY-NC license

Mater. Adv., 2020,1, 3597-3604

Oxidative ionothermal synthesis for micro and macro Zn-based materials

F. Malaret, J. Hallett and K. S. Campbell, Mater. Adv., 2020, 1, 3597 DOI: 10.1039/D0MA00660B

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