Issue 48, 2020

Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species

Abstract

Transition metal borylene complexes of the type [(OC)5M[double bond, length as m-dash]BN(SiMe3)(tBu)] (M = Cr, Mo, W) have been synthesised by salt elimination of the corresponding dibromoborane and the dianionic metallates Na2[M(CO)5]. The borylene complexes have been characterised by multinuclear solution-state NMR spectroscopy and solid-state molecular structure determination. The group 6 borylene complexes can be used to effectively transfer the borylene ligand to other transition metal complexes by replacing one or two carbonyl ligands upon irradiation of the reaction mixture with UV light. This borylene transfer reaction led to the formation of new terminal and bridging borylene complexes which cannot be formed by the corresponding salt elimination reactions, including a rare example of a bis(terminal borylene) complex and only the second reported terminal borylene complex of an early transition metal (vanadium).

Graphical abstract: Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species

Supplementary files

Article information

Article type
Paper
Submitted
14 Okt. 2020
Accepted
12 Nov. 2020
First published
13 Nov. 2020

Dalton Trans., 2020,49, 17719-17724

Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species

B. B. Macha, D. Dhara, K. Radacki, R. D. Dewhurst and H. Braunschweig, Dalton Trans., 2020, 49, 17719 DOI: 10.1039/D0DT03557B

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