Issue 70, 2020

Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(ii) iodide ion-triplet complex

Abstract

A combination of pillar[5]-bis-trithiacrown (L) and mercury(II) halides afforded a monomer complex (Cl-form), a 1-D coordination polymer (Br-form) and a supramolecular ion-triplet complex [(I·Hg·I)@L] (I-form). In the ion-triplet complex, the host encapsulates the (I–Hg2+–I) entity via Hg2+⋯π and C–H⋯I interactions, reflecting geometrical complementarity.

Graphical abstract: Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(ii) iodide ion-triplet complex

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
03 Jūn. 2020
Accepted
24 Jūl. 2020
First published
24 Jūl. 2020

Chem. Commun., 2020,56, 10135-10138

Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(II) iodide ion-triplet complex

M. Shin, S. Seo, I. Park, E. Lee, Y. Habata and S. S. Lee, Chem. Commun., 2020, 56, 10135 DOI: 10.1039/D0CC03902K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements