Issue 67, 2020

A recyclable metal–organic framework for ammonia vapour adsorption

Abstract

Herein, we present a new strategy to design metal–organic frameworks (MOFs) as adsorbents for ammonia (NH3) vapour. The linking ligand is functionalized with a sterically hindered Lewis acidic boron (B) centre, allowing efficient capture of NH3 and easy recycling of the MOF by simply heating at low temperature. The recycled MOF material can be used for NH3 capture for at least 5 cycles without losing its crystallinity or its luminescence properties.

Graphical abstract: A recyclable metal–organic framework for ammonia vapour adsorption

Supplementary files

Article information

Article type
Communication
Submitted
29 Janv. 2020
Accepted
17 Jūl. 2020
First published
17 Jūl. 2020

Chem. Commun., 2020,56, 9600-9603

A recyclable metal–organic framework for ammonia vapour adsorption

T. N. Nguyen, I. M. Harreschou, J. Lee, K. C. Stylianou and D. W. Stephan, Chem. Commun., 2020, 56, 9600 DOI: 10.1039/D0CC00741B

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