Issue 13, 2019

Noncovalent and covalent double assembly: unravelling a unified mechanism for the tubular shape evolution of microporous organic polymers

Abstract

This work unravels the unified mechanistic principle of the tubular shape evolution of microporous organic polymers (MOPs) prepared by the Sonogashira coupling of ethynylarenes and haloarenes. Using ionic building blocks (self-templates), in situ generated salts (in situ templates), or salt additives (additive templates), tubular MOP materials could be engineered. The assembled ionic species can act as morphology templates in the covalent assembly of building blocks to form MOP tubes.

Graphical abstract: Noncovalent and covalent double assembly: unravelling a unified mechanism for the tubular shape evolution of microporous organic polymers

Supplementary files

Article information

Article type
Paper
Submitted
14 Janv. 2019
Accepted
01 Marts 2019
First published
01 Marts 2019

J. Mater. Chem. A, 2019,7, 7859-7866

Noncovalent and covalent double assembly: unravelling a unified mechanism for the tubular shape evolution of microporous organic polymers

C. W. Kang, J. H. Ko, S. M. Lee, H. J. Kim, Y. Ko and S. U. Son, J. Mater. Chem. A, 2019, 7, 7859 DOI: 10.1039/C9TA00464E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements