Issue 6, 2019

Understanding the noble metal modifying effect on In2O3 nanowires: highly sensitive and selective gas sensors for potential early screening of multiple diseases

Abstract

Detection of multiple volatile organic compounds in human exhaled breath using semiconductor oxide-based sensing devices has attracted increasing attention for the early diagnosis of diseases. However, detecting trace levels of exhaled biomarkers with high sensitivity and selectivity remains a challenge and the corresponding mechanism for the selectivity is still unclear. Herein, ultrafine In2O3 nanowires (NWs) modified with Au, Ag, and Pt noble metal nanoparticles (NMNPs) are synthesized using the electrospinning method and are used to build semiconductor sensors. It is exciting to observe that the introduction of NMNPs can not only enhance the sensing performance, but also effectively adjust the selectivity. The Au-, Ag- and Pt-modified In2O3 NW sensors exhibit excellent selectivity to hydrogen sulfide, formaldehyde, and acetone biomarkers, respectively. To completely understand the mechanism, theoretical simulation is performed based on density functional theory, which demonstrated that the specific absorption energies between the modified In2O3 NWs and the target gases along with the “spillover effect” resulted in excellent specific selectivity. Importantly, the NMNP modified In2O3 NW sensors are successfully used to build a sensor array for effective simultaneous detection of simulated exhaled breath. The present work provides a simple, low-cost, effective tool for early screening of halitosis, breast cancer, and diabetes at the same time and an in-depth understanding of the enhanced sensing performance by the introduction of NMNPs.

Graphical abstract: Understanding the noble metal modifying effect on In2O3 nanowires: highly sensitive and selective gas sensors for potential early screening of multiple diseases

Supplementary files

Article information

Article type
Communication
Submitted
18 Jūn. 2019
Accepted
25 Jūl. 2019
First published
25 Jūl. 2019

Nanoscale Horiz., 2019,4, 1361-1371

Understanding the noble metal modifying effect on In2O3 nanowires: highly sensitive and selective gas sensors for potential early screening of multiple diseases

W. Liu, J. Sun, L. Xu, S. Zhu, X. Zhou, S. Yang, B. Dong, X. Bai, G. Lu and H. Song, Nanoscale Horiz., 2019, 4, 1361 DOI: 10.1039/C9NH00404A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements