Issue 8, 2019

A Ag nanoparticle functionalized Sg-C3N4/Bi2O3 2D nanohybrid: a promising visible light harnessing photocatalyst towards degradation of rhodamine B and tetracycline

Abstract

In the present work, S doped graphitic carbon nitride (Sg-C3N4) 2D nanosheets were synthesized by performing a thermal polymerization reaction of thiourea at 500 °C. After that the surface of Sg-C3N4 was functionalized with Bi2O3/Ag composite nanoparticles via a chemical precipitation method followed by heat treatment at 330 °C. The prepared Sg-C3N4/Bi2O3/Ag ternary nanocomposites were used as a visible light active photocatalyst for catalytic degradation of rhodamine B (RhB) dye and tetracycline hydrochloride, under natural solar light. The prepared ternary nanocomposites were characterized by using UV-Vis DRS, FT-IR, FESEM, EDX, TEM, XRD, photoluminescence (PL), electrochemical impedance spectroscopy and XPS analytical techniques. The XRD, UV-Vis DRS and FT-IR studies clearly revealed the formation of ternary phases in the composites. From the TEM and EDX studies it was clearly observed that spherical Ag nanoparticles (5–10 nm) and irregular Bi2O3 particles (60–120 nm) were decorated on the surface of 2D S doped g-C3N4 nanosheets. XPS studies also confirmed the formation of the ternary nanocomposite system. The results from the photocatalytic degradation of RhB dye revealed that 95% of the RhB dye was decolorized within 90 min of contact time by Sg-C3N4/Bi2O3/Ag ternary nanocomposites under natural solar light. Among the different prepared photocatalysts, Sg-C3N4/Bi2O3/Ag (15%) was found to be the most efficient photocatalyst towards the decolourization of RhB dye. This result is ascribed to the optimum loading of Ag, formation of a hetero-junction between the ternary phases, more light harvesting capacity and the lowest recombination rate of charge carriers. Apart from the coloured RhB dye, the photocatalytic degradation of the non-coloured tetracycline hydrochloride (TCH) compound was also studied to understand the photosensitization effect on the degradation process. Again scavenger studies were also performed in order to understand the mechanism of photodegradation. It was observed that along with the electron and hole pairs generated by light photons, hydroxide radicals play an important role in the degradation mechanism. The reusability study indicates that the photocatalysts prepared were highly stable at room temperature and can be recycled and reused for up to four successful cycles without a major loss in their performance.

Graphical abstract: A Ag nanoparticle functionalized Sg-C3N4/Bi2O3 2D nanohybrid: a promising visible light harnessing photocatalyst towards degradation of rhodamine B and tetracycline

Supplementary files

Article information

Article type
Paper
Submitted
20 Marts 2019
Accepted
02 Jūl. 2019
First published
03 Jūl. 2019
This article is Open Access
Creative Commons BY-NC license

Nanoscale Adv., 2019,1, 3212-3224

A Ag nanoparticle functionalized Sg-C3N4/Bi2O3 2D nanohybrid: a promising visible light harnessing photocatalyst towards degradation of rhodamine B and tetracycline

S. Padhiari and G. Hota, Nanoscale Adv., 2019, 1, 3212 DOI: 10.1039/C9NA00172G

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements