Issue 39, 2019

CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation

Abstract

We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.

Graphical abstract: CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation

Supplementary files

Article information

Article type
Communication
Submitted
28 Jūl. 2019
Accepted
03 Sept. 2019
First published
04 Sept. 2019

Dalton Trans., 2019,48, 14580-14584

CO2 activation by manganese pincer complexes through different modes of metal–ligand cooperation

A. Kumar, P. Daw, N. A. Espinosa-Jalapa, G. Leitus, L. J. W. Shimon, Y. Ben-David and D. Milstein, Dalton Trans., 2019, 48, 14580 DOI: 10.1039/C9DT03088C

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