Issue 11, 2019

Solvent-free anhydrous Li+, Na+ and K+ salts of [B(3,5-(CF3)2C6H3)4], [BArF4]. Improved synthesis and solid-state structures

Abstract

A modified, convenient, preparation of solvent-free, anhydrous, Li+, Na+ and K+ salts of the ubiquitous [BArF4] anion is reported, that involves a simple additional recrystallisation step. Anhydrous Na[BArF4], K[BArF4], and [Li(H2O)][BArF4], were characterised by single-crystal X-ray diffraction.

Graphical abstract: Solvent-free anhydrous Li+, Na+ and K+ salts of [B(3,5-(CF3)2C6H3)4]−, [BArF4]−. Improved synthesis and solid-state structures

Supplementary files

Article information

Article type
Communication
Submitted
17 Janv. 2019
Accepted
30 Janv. 2019
First published
14 Febr. 2019
This article is Open Access
Creative Commons BY license

Dalton Trans., 2019,48, 3551-3554

Solvent-free anhydrous Li+, Na+ and K+ salts of [B(3,5-(CF3)2C6H3)4], [BArF4]. Improved synthesis and solid-state structures

A. J. Martínez-Martínez and A. S. Weller, Dalton Trans., 2019, 48, 3551 DOI: 10.1039/C9DT00235A

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