Issue 16, 2019

Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

Abstract

Intramolecular aminations of C–H bonds represent an elegant synthetic way to form important N-heterocycles. If suitable nitrene precursors are employed, organometallic complexes are able to catalyze the C–H amination under mild conditions. In the past years, Fe catalysis has emerged as a vigorously developing new (old) discipline. The present review highlights the most important developments in this field through a systematic differentiation between open-shell (radical) and closed-shell (non-radical) mechanisms.

Graphical abstract: Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

Article information

Article type
Minireview
Submitted
09 Apr. 2019
Accepted
03 Jūl. 2019
First published
03 Jūl. 2019

Catal. Sci. Technol., 2019,9, 4188-4197

Recent advances in Fe-catalyzed C–H aminations using azides as nitrene precursors

B. Plietker and A. Röske, Catal. Sci. Technol., 2019, 9, 4188 DOI: 10.1039/C9CY00675C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements