Issue 89, 2019

Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(ii)–Pheox complex

Abstract

This work reports the first efficient enantioselective intramolecular Buchner reaction of diazoacetamides. The Ru(II)–Pheox catalyst was shown to be highly efficient in this transformation in terms of both the regio- and enantioselectivity (up to 99% ee) giving the desired products in quantitative yield.

Graphical abstract: Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(ii)–Pheox complex

Supplementary files

Article information

Article type
Communication
Submitted
04 Sept. 2019
Accepted
09 Okt. 2019
First published
10 Okt. 2019

Chem. Commun., 2019,55, 13398-13401

Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(II)–Pheox complex

N. Phan Thi Thanh, M. Tone, H. Inoue, I. Fujisawa and S. Iwasa, Chem. Commun., 2019, 55, 13398 DOI: 10.1039/C9CC06889A

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