Issue 79, 2019

Synthesis of o-carborane-functionalized metal–organic frameworks through ligand exchanges for aggregation-induced emission in the solid state

Abstract

The carborane (CB)-functionalized ligand was installed in a variety of MOFs through postsynthetic ligand exchange processes. This methodology is a general method for preparing o-CB-functionalized MOFs with known frameworks. Furthermore, the photoluminescence (PL) spectra revealed intriguing aggregation-induced emission (AIE) features following the systematic incorporation of o-CB functionalities into framework-type materials.

Graphical abstract: Synthesis of o-carborane-functionalized metal–organic frameworks through ligand exchanges for aggregation-induced emission in the solid state

Supplementary files

Article information

Article type
Communication
Submitted
17 Aug. 2019
Accepted
06 Sept. 2019
First published
09 Sept. 2019

Chem. Commun., 2019,55, 11844-11847

Synthesis of o-carborane-functionalized metal–organic frameworks through ligand exchanges for aggregation-induced emission in the solid state

S. Choi, H. Lee, C. H. Ryu, J. Lee, J. Lee, M. Yoon, Y. Kim, M. H. Park, K. M. Lee and M. Kim, Chem. Commun., 2019, 55, 11844 DOI: 10.1039/C9CC06386B

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