Issue 85, 2019

High affinity threading of a new tetralactam macrocycle in water by fluorescent deep-red and near-infrared squaraine dyes

Abstract

A new tetralactam macrocycle was prepared and found to encapsulate deep-red and near-infrared squaraine and croconaine dyes in water with tunable threading kinetics. The new supramolecular paradigm of guest back-folding was used to increase macrocycle/squaraine affinity by 370-fold and achieve an association constant of 2.8 × 109 M−1.

Graphical abstract: High affinity threading of a new tetralactam macrocycle in water by fluorescent deep-red and near-infrared squaraine dyes

Supplementary files

Article information

Article type
Communication
Submitted
08 Jūl. 2019
Accepted
20 Sept. 2019
First published
08 Okt. 2019

Chem. Commun., 2019,55, 12793-12796

High affinity threading of a new tetralactam macrocycle in water by fluorescent deep-red and near-infrared squaraine dyes

J. M. Dempsey, C. Zhai, H. H. McGarraugh, C. L. Schreiber, S. E. Stoffel, A. Johnson and B. D. Smith, Chem. Commun., 2019, 55, 12793 DOI: 10.1039/C9CC05244E

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