Issue 1, 2019

Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates

Abstract

A palladium-catalyzed oxidative borylation reaction of conjugated enynones is developed. This reaction represents a new method for the synthesis of furyl-substituted alkenylboronates. The reaction works well with a series of conjugated enynones. Boryl migratory insertion of the palladium carbene intermediate is proposed as the key step in these transformations.

Graphical abstract: Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates

Supplementary files

Article information

Article type
Communication
Submitted
13 Nov. 2018
Accepted
24 Nov. 2018
First published
26 Nov. 2018

Chem. Commun., 2019,55, 59-62

Palladium-catalyzed oxidative borylation of conjugated enynones through carbene migratory insertion: synthesis of furyl-substituted alkenylboronates

Y. Ping, T. Chang, K. Wang, J. Huo and J. Wang, Chem. Commun., 2019, 55, 59 DOI: 10.1039/C8CC09024F

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