Issue 12, 2019

Photoenzymatic epoxidation of styrenes

Abstract

Two-component-diffusible-flavomonooxygenases are versatile biocatalysts for selective epoxidation-, hydroxylation- or halogenation reactions. Their complicated molecular architecture can be simplified using photochemical regeneration of the catalytically active, reduced FADH2 prosthetic group. In this contribution we provide the proof-of-concept and characterization for the direct regeneration of the styrene monooxygenase from Pseudomonas.

Graphical abstract: Photoenzymatic epoxidation of styrenes

Supplementary files

Article information

Article type
Communication
Submitted
11 Okt. 2018
Accepted
18 Dec. 2018
First published
22 Janv. 2019
This article is Open Access
Creative Commons BY license

Chem. Commun., 2019,55, 1790-1792

Photoenzymatic epoxidation of styrenes

M. M. C. H. van Schie, C. E. Paul, I. W. C. E. Arends and F. Hollmann, Chem. Commun., 2019, 55, 1790 DOI: 10.1039/C8CC08149B

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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