Issue 10, 2018

Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts

Abstract

A copper-catalyzed direct C–H arylation or vinylation of BODIPYs at the β-position by iodonium salts has been developed, which provides facile access to a variety of mono-substituted BODIPY dyes. Interestingly, β-styryl BODIPY compound 9b exhibits apparent cytotoxicity after laser irradiation, which has great potential for photodynamic therapy.

Graphical abstract: Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts

Supplementary files

Article information

Article type
Paper
Submitted
05 Dec. 2017
Accepted
27 Janv. 2018
First published
01 Febr. 2018
This article is Open Access
Creative Commons BY license

RSC Adv., 2018,8, 5542-5549

Direct C–H functionalization of difluoroboron dipyrromethenes (BODIPYs) at β-position by iodonium salts

W. Ren, H. Xiang, C. Peng, Z. Musha, J. Chen, X. Li, R. Huang and Y. Hu, RSC Adv., 2018, 8, 5542 DOI: 10.1039/C7RA13070H

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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