Issue 1, 2018

A solution-processable dissymmetric porous organic cage

Abstract

Two dissymmetric racemic analogues of the chiral porous organic cage, CC3, were isolated and unambiguously characterised as a racemate pair of the R,R,R,S,S,S and S,S,S,R,R,R-diastereomers (CC3-RS and CC3-SR). CC3-RS/CC3-SR equals the highest porosity measured for CC3 but is an order of magnitude more soluble, making it an excellent candidate for incorporation into a membrane for separation applications.

Graphical abstract: A solution-processable dissymmetric porous organic cage

Supplementary files

Article information

Article type
Paper
Submitted
04 Sept. 2017
Accepted
09 Okt. 2017
First published
22 Nov. 2017
This article is Open Access
Creative Commons BY license

Mol. Syst. Des. Eng., 2018,3, 223-227

A solution-processable dissymmetric porous organic cage

A. G. Slater, M. A. Little, M. E. Briggs, K. E. Jelfs and A. I. Cooper, Mol. Syst. Des. Eng., 2018, 3, 223 DOI: 10.1039/C7ME00090A

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