Issue 98, 2018

Moderate supercritical synthesis as a facile route to mixed-valent uranium(iv,v) and (v,vi) silicates

Abstract

Mixed-valent uranium(IV,V) and (V,VI) phases represent a unique subset of known uranium compounds. Efforts to develop our current understanding of these materials have pointed to hydrothermal methods as effective preparative techniques. Herein we report the successful use of moderate supercritical conditions for the synthesis of five new U(V) containing phases.

Graphical abstract: Moderate supercritical synthesis as a facile route to mixed-valent uranium(iv,v) and (v,vi) silicates

Supplementary files

Article information

Article type
Communication
Submitted
28 Sept. 2018
Accepted
18 Okt. 2018
First published
18 Okt. 2018

Chem. Commun., 2018,54, 13794-13797

Author version available

Moderate supercritical synthesis as a facile route to mixed-valent uranium(IV,V) and (V,VI) silicates

K. A. Pace, V. V. Klepov, G. Morrison and H. zur Loye, Chem. Commun., 2018, 54, 13794 DOI: 10.1039/C8CC07789D

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