Issue 92, 2018

Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11

Abstract

Large crystals of Yb14MgSb11 were grown through a Sn flux method. Magnetic susceptibility measurements yield an effective magnetic moment of 3.4(1) μB, revealing the presence of both divalent and trivalent Yb in Yb14MgSb11. Previously assumed to only contain Yb2+ as in Yb14MnSb11, the mixed valency demonstrates that Yb14MgSb11 is a Zintl phase.

Graphical abstract: Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11

Supplementary files

Article information

Article type
Communication
Submitted
06 Jūl. 2018
Accepted
17 Okt. 2018
First published
25 Okt. 2018

Chem. Commun., 2018,54, 12946-12949

Author version available

Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11

E. L. Kunz Wille, N. H. Jo, J. C. Fettinger, P. C. Canfield and S. M. Kauzlarich, Chem. Commun., 2018, 54, 12946 DOI: 10.1039/C8CC05471A

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