Issue 46, 2018

Covalent switching, involving divinylbenzene ligands within 3D coordination polymers, indicated by changes in fluorescence

Abstract

Reversible cycloaddition reactions between 1,4-bis[2-(3-pyridyl)ethenyl]benzene and its photodimers were performed within a pair of three-dimensional coordination polymers with retention of single crystal character. In each case, switching between two crystalline forms could be followed by monitoring the flourescence behaviour.

Graphical abstract: Covalent switching, involving divinylbenzene ligands within 3D coordination polymers, indicated by changes in fluorescence

Supplementary files

Article information

Article type
Communication
Submitted
05 Apr. 2018
Accepted
08 Maijs 2018
First published
09 Maijs 2018

Chem. Commun., 2018,54, 5831-5834

Covalent switching, involving divinylbenzene ligands within 3D coordination polymers, indicated by changes in fluorescence

N. Li, D. Liu, B. F. Abrahams and J. Lang, Chem. Commun., 2018, 54, 5831 DOI: 10.1039/C8CC02743A

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