Issue 12, 2018

Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions

Abstract

Bench-stable solid triorganoindium compounds have been prepared by coordination with 4-(dimethylamino)pyridine (DMAP). The solid R3In(DMAP) complexes are obtained from the corresponding solution of R3In in quantitative yield and can be stored for up to several weeks. These reagents show excellent reactivity in palladium-catalyzed cross-coupling reactions with organic electrophiles.

Graphical abstract: Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions

Supplementary files

Article information

Article type
Communication
Submitted
05 Dec. 2017
Accepted
11 Janv. 2018
First published
12 Janv. 2018

Chem. Commun., 2018,54, 1453-1456

Synthesis of bench-stable solid triorganoindium reagents and reactivity in palladium-catalyzed cross-coupling reactions

J. M. Gil-Negrete, J. Pérez Sestelo and L. A. Sarandeses, Chem. Commun., 2018, 54, 1453 DOI: 10.1039/C7CC09344F

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