Issue 47, 2017

Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

Abstract

A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.

Graphical abstract: Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

Supplementary files

Article information

Article type
Communication
Submitted
14 Sept. 2017
Accepted
17 Okt. 2017
First published
18 Okt. 2017

J. Mater. Chem. A, 2017,5, 24580-24584

Discovery of a novel, large pore phase in a bimetallic Al/V metal–organic framework

H. Depauw, I. Nevjestić, G. Wang, K. Leus, F. Callens, E. De Canck, K. De Buysser, H. Vrielinck and P. Van Der Voort, J. Mater. Chem. A, 2017, 5, 24580 DOI: 10.1039/C7TA08103K

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