Issue 10, 2017

Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)

Abstract

The Fe-catalyzed insertion of fluoromethylcarbenes including trifluoromethylcarbene and difluoromethylcarbene generated in situ from sulfonium salts (Ph2S+CH2CF3OTf and Ph2S+CH2CF2H OTf) into X–H (X = Si, C and P) bonds is described. The insertion of both carbenes into the Si–H bond occurred smoothly, and trifluoromethylcarbene could also insert into C–H and P–H bonds.

Graphical abstract: Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)

Supplementary files

Article information

Article type
Research Article
Submitted
01 Jūn. 2017
Accepted
19 Jūn. 2017
First published
20 Jūn. 2017

Org. Chem. Front., 2017,4, 1917-1920

Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)

Y. Duan, J. Lin, J. Xiao and Y. Gu, Org. Chem. Front., 2017, 4, 1917 DOI: 10.1039/C7QO00430C

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