Issue 4, 2017

Enhanced magnetic anisotropy in a tellurium-coordinated cobalt single-ion magnet

Abstract

A series of tetrahedral Co(II) complexes with chalcogen donors were prepared, which exhibited strong magnetic uniaxial anisotropies and slow relaxations as SIMs. By substituting donors from S to Te, we realized the fine-tuning of the ligand field while keeping the coordination geometry virtually unchanged, yielding the first tellurium-coordinated SIM.

Graphical abstract: Enhanced magnetic anisotropy in a tellurium-coordinated cobalt single-ion magnet

Supplementary files

Article information

Article type
Research Article
Submitted
30 Nov. 2016
Accepted
27 Janv. 2017
First published
08 Febr. 2017

Inorg. Chem. Front., 2017,4, 701-705

Enhanced magnetic anisotropy in a tellurium-coordinated cobalt single-ion magnet

X. Yao, M. Yang, J. Xiong, J. Liu, C. Gao, Y. Meng, S. Jiang, B. Wang and S. Gao, Inorg. Chem. Front., 2017, 4, 701 DOI: 10.1039/C6QI00543H

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