Issue 17, 2017

Complexes of Ni(i): a “rare” oxidation state of growing importance

Abstract

Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as well as in chemical applications such as the catalytic transformation of organic substrates. Despite nickel's importance, the investigation of its compounds in various oxidation states remains uneven and those in the +1 oxidation are less common than those in the neighboring 0 and +2 oxidation states. Nonetheless, in recent years, the volume of work on Ni(I) complexes has increased to the extent that they can be no longer regarded as rare. This review focuses on the syntheses and structures of Ni(I) complexes and shows that they display a range of structures, reactivity and magnetic behavior that places them in the forefront of current nickel chemistry research.

Graphical abstract: Complexes of Ni(i): a “rare” oxidation state of growing importance

Article information

Article type
Review Article
Submitted
24 Marts 2017
First published
04 Jūl. 2017

Chem. Soc. Rev., 2017,46, 5347-5399

Complexes of Ni(I): a “rare” oxidation state of growing importance

C. Lin and P. P. Power, Chem. Soc. Rev., 2017, 46, 5347 DOI: 10.1039/C7CS00216E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements