Issue 29, 2017

Using water adsorption measurements to access the chemistry of defects in the metal–organic framework UiO-66

Abstract

Tailoring defects in metal–organic frameworks is important for enhancing sorption and reaction properties. Defects in UiO-66 have been characterized for the first time by using water adsorption measurements. We found that the defect-induced hydrophilicity, quantitatively expressed by the Henry constant and the saturation water uptake, correlates well with the catalytic performance in the cyanosilylation of benzaldehyde.

Graphical abstract: Using water adsorption measurements to access the chemistry of defects in the metal–organic framework UiO-66

Supplementary files

Article information

Article type
Communication
Submitted
31 Janv. 2017
Accepted
23 Febr. 2017
First published
23 Febr. 2017

CrystEngComm, 2017,19, 4137-4141

Using water adsorption measurements to access the chemistry of defects in the metal–organic framework UiO-66

S. Dissegna, R. Hardian, K. Epp, G. Kieslich, M. Coulet, P. Llewellyn and R. A. Fischer, CrystEngComm, 2017, 19, 4137 DOI: 10.1039/C7CE00224F

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