Issue 11, 2017

A novel methoxy-decorated metal–organic framework exhibiting high acetylene and carbon dioxide storage capacities

Abstract

A methoxy-decorated novel metal–organic framework (MOF), Cu2(DTPD) (ZJU-12, H4DTPD = 5,5′-(2,6-dimethoxynaphthalene-1,5-diyl)diisophthalic acid) with optimized pore space and open metal sites, was solvothermally synthesized and structurally characterized. The activated ZJU-12a displays a moderately high BET (Brunauer–Emmett–Teller) surface area of 2316 m2 g−1. Due to the pore size of the crystal being consistent with the molecular size and kinetic diameters of C2H2 and CO2, ZJU-12a exhibits a high C2H2 storage capacity of 244 cm3 g−1 and CO2 capture capacity of 134 cm3 g−1 at room temperature.

Graphical abstract: A novel methoxy-decorated metal–organic framework exhibiting high acetylene and carbon dioxide storage capacities

Supplementary files

Article information

Article type
Paper
Submitted
02 Nov. 2016
Accepted
28 Dec. 2016
First published
28 Dec. 2016

CrystEngComm, 2017,19, 1464-1469

A novel methoxy-decorated metal–organic framework exhibiting high acetylene and carbon dioxide storage capacities

X. Duan, Y. Cui, Y. Yang and G. Qian, CrystEngComm, 2017, 19, 1464 DOI: 10.1039/C6CE02291J

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