The first example of gold-catalyzed addition of Sn–Sn bonds to alkynes is reported. A cationic gold(I) complex bearing a phosphite ligand is reported to efficiently catalyze the bis(stannylation) of propiolates with hexabutylditin under mild conditions.
F. Chahdoura, N. Lassauque, D. Bourissou and A. Amgoune, Org. Chem. Front., 2016, 3, 856 DOI: 10.1039/C6QO00128A
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