Issue 6, 2016

Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

Abstract

Photocatalytic hydrodefluorination of perfluoroarenes by rhodium porphyrin complexes with high tolerance to various functional groups has been developed. Mechanistic studies reveal that the rhodium aryl complex, (por)Rh-C6F4R, is the key intermediate.

Graphical abstract: Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

Supplementary files

Article information

Article type
Research Article
Submitted
01 Dec. 2015
Accepted
31 Marts 2016
First published
05 Apr. 2016

Inorg. Chem. Front., 2016,3, 861-865

Light induced catalytic hydrodefluorination of perfluoroarenes by porphyrin rhodium

X. Liu, Z. Wang, X. Zhao and X. Fu, Inorg. Chem. Front., 2016, 3, 861 DOI: 10.1039/C5QI00269A

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