Issue 24, 2016

Insertion of tBuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry

Abstract

The reactivity of thorium–phosphido and thorium–arsenido bonds was probed using tert-butyl isocyanide, tBuNC. Reaction of (C5Me5)2Th[E(H)R]2, E = P, As; R = 2,4,6-iPr3C6H2, 2,4,6-Me3C6H2 with tBuNC affords the first phosphaazaallene and arsaazaallene moieties with an f-element.

Graphical abstract: Insertion of tBuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry

Supplementary files

Article information

Article type
Paper
Submitted
26 Febr. 2016
Accepted
13 Apr. 2016
First published
28 Apr. 2016
This article is Open Access
Creative Commons BY license

Dalton Trans., 2016,45, 10042-10049

Insertion of tBuNC into thorium–phosphorus and thorium–arsenic bonds: phosphaazaallene and arsaazaallene moieties in f element chemistry

A. C. Behrle and J. R. Walensky, Dalton Trans., 2016, 45, 10042 DOI: 10.1039/C6DT00776G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements