Issue 84, 2016

Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)2XF6 (X = P, As, Sb)

Abstract

Control of the structural type in metallic enantiopure and racemic radical cation salts is achieved through hydrogen bonding interactions between the chiral donor DM-EDT-TTF and the XF6 anions (X = P, As, Sb), determined by the anion size and the chiral information.

Graphical abstract: Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)2XF6 (X = P, As, Sb)

Supplementary files

Article information

Article type
Communication
Submitted
15 Aug. 2016
Accepted
27 Sept. 2016
First published
27 Sept. 2016
This article is Open Access
Creative Commons BY license

Chem. Commun., 2016,52, 12438-12441

Anion size control of the packing in the metallic versus semiconducting chiral radical cation salts (DM-EDT-TTF)2XF6 (X = P, As, Sb)

F. Pop, P. Auban-Senzier, E. Canadell and N. Avarvari, Chem. Commun., 2016, 52, 12438 DOI: 10.1039/C6CC06706A

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