Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

Anton Peristyy; Pavel N. Nesterenko; Anita Das; Deanna M. D'Alessandro; Emily F. Hilder; R. Dario Arrua

doi:10.1039/C6CC00111D

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents†

Anton Peristyy,^a Pavel N. Nesterenko,^a Anita Das,^b Deanna M. D'Alessandro,^b Emily F. Hilder^a and R. Dario Arrua*^a

Author affiliations

* Corresponding authors

^a Australian Centre for Research on Separation Science, University of Tasmania, Private Bag 75, Hobart, TAS 7001, Australia
E-mail: Dario.Arrua@utas.edu.au, Dario.Arrua@unisa.edu.au

^b School of Chemistry F11, University of Sydney, NSW 2006, Australia

Abstract

A new flow-dependent separation selectivity (FDSS) effect was discovered in isocratic HPLC. Significant changes in chromatographic selectivity were achieved by simple variation of the mobile phase flow rate. The FDSS effect was observed for a core–shell stationary phase using silica particles as a core and a Zr-based metal–organic framework (UiO-66) as a shell.

This article is part of the themed collection: Celebrating the ChemComm Emerging Investigator Lectureship Winners

Download options Please wait...

Supplementary files

Supplementary information PDF (538K)

Article information

DOI: https://doi.org/10.1039/C6CC00111D
Article type: Communication
Submitted: 06 Janv. 2016
Accepted: 18 Marts 2016
First published: 18 Marts 2016
This article is Open Access

Download Citation

Chem. Commun., 2016,52, 5301-5304

Permissions

Request permissions

Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

A. Peristyy, P. N. Nesterenko, A. Das, D. M. D'Alessandro, E. F. Hilder and R. D. Arrua, Chem. Commun., 2016, 52, 5301 DOI: 10.1039/C6CC00111D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Flow-dependent separation selectivity for organic molecules on metal–organic frameworks containing adsorbents

Social activity

Search articles by author

Spotlight

Advertisements