Issue 32, 2015

A one-step route to solubilised, purified or functionalised single-walled carbon nanotubes

Abstract

Reductive dissolution is a promising processing route for single walled carbon nanotubes (SWCNTs) that avoids the damage caused by ultrasonication and aggressive oxidation whilst simultaneously allowing access to a wealth of SWCNT functionalisation reactions. Here, reductive dissolution has been simplified to a single one-pot reaction through the use of sodium naphthalide in dimethylacetamide allowing direct synthesis of SWCNT Na+ solutions. Gram quantities of SWCNTs can be dissolved at concentrations over 2 mg mL−1. These reduced SWCNT solutions can easily be functionalised through the addition of alkyl halides; reducing steric bulk of the grafting moiety and increasing polarisability of the leaving group increases the extent of functionalisation. An optimised absolute sodium concentration of 25 mM is shown to be more important than carbon to metal ratio in determining the maximum degree of functionalisation. This novel dissolution system can be modified for use as a non-destructive purification route for raw SWCNT powder by adjusting the degree of charging to dissolve carbonaceous impurities, catalyst particles and defective material, before processing the remaining SWCNTs.

Graphical abstract: A one-step route to solubilised, purified or functionalised single-walled carbon nanotubes

Supplementary files

Article information

Article type
Paper
Submitted
14 Maijs 2015
Accepted
07 Jūl. 2015
First published
10 Jūl. 2015
This article is Open Access
Creative Commons BY license

J. Mater. Chem. A, 2015,3, 16708-16715

Author version available

A one-step route to solubilised, purified or functionalised single-walled carbon nanotubes

A. J. Clancy, J. Melbourne and M. S. P. Shaffer, J. Mater. Chem. A, 2015, 3, 16708 DOI: 10.1039/C5TA03561A

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements