Issue 3, 2014

Ru(ii)-catalyzed rearrangement of the allenic sulfide bearing propargyl moiety: efficient formation of benzene derivatives

Abstract

[RuCl2(p-cymene)]2 efficiently catalyzes the rearrangement of allenic sulfides bearing the propargyl moiety to afford 1,2,4-trisubstituted benzene derivatives. The alkyne-Ru(II) carbene [2 + 2] cycloaddition/ring opening process has been proposed in the reaction mechanism.

Graphical abstract: Ru(ii)-catalyzed rearrangement of the allenic sulfide bearing propargyl moiety: efficient formation of benzene derivatives

Supplementary files

Article information

Article type
Research Article
Submitted
02 Janv. 2014
Accepted
21 Janv. 2014
First published
07 Febr. 2014

Org. Chem. Front., 2014,1, 235-239

Author version available

Ru(II)-catalyzed rearrangement of the allenic sulfide bearing propargyl moiety: efficient formation of benzene derivatives

L. Peng, X. Zhang, J. Ma and J. Wang, Org. Chem. Front., 2014, 1, 235 DOI: 10.1039/C4QO00001C

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