Oxidative C–H amination reactions

Abstract

Towards “Oxidative-Ullmann–Goldberg” and “Oxidative-Buchwald–Hartwig” type amination reactions. This review focuses on the newly developed oxidative C–N bond formation techniques, applicable in the field of organic synthesis. Particular emphasis is given to those which are classified as cross-dehydrogenative-couplings, through dual C–H and N–H activation, thus formally extruding “H₂” as a by-product.