Issue 72, 2014

Potential-driven molecular tiling of a charged polycyclic aromatic compound

Abstract

Using in situ electrochemical scanning tunnelling microscopy (EC-STM), we demonstrate fully reversible tuning of molecular tiling between self-assembled structures with supramolecular motifs containing 2, 3, 4, 6 or 7 tectons. The structures can be explained by electrocompression of the cationic adlayer at the solid–liquid interface.

Graphical abstract: Potential-driven molecular tiling of a charged polycyclic aromatic compound

Supplementary files

Article information

Article type
Communication
Submitted
01 Jūn. 2014
Accepted
11 Jūl. 2014
First published
31 Jūl. 2014

Chem. Commun., 2014,50, 10376-10378

Potential-driven molecular tiling of a charged polycyclic aromatic compound

K. Cui, O. Ivasenko, K. S. Mali, D. Wu, X. Feng, K. Müllen, S. De Feyter and S. F. L. Mertens, Chem. Commun., 2014, 50, 10376 DOI: 10.1039/C4CC04189E

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