Issue 40, 2014

Rhodium-catalyzed carbene transfer to alkynes via 2-furylcarbenes generated from enynones

Abstract

A rhodium-catalyzed carbene transfer to alkynes is reported. Easily available enynones served as the carbene source replacing diazocompounds. The overall process involved a cyclization–cyclopropenation–ring enlargement sequence.

Graphical abstract: Rhodium-catalyzed carbene transfer to alkynes via 2-furylcarbenes generated from enynones

Supplementary files

Article information

Article type
Communication
Submitted
30 Sept. 2013
Accepted
15 Okt. 2013
First published
17 Okt. 2013

Chem. Commun., 2014,50, 5379-5381

Rhodium-catalyzed carbene transfer to alkynes via 2-furylcarbenes generated from enynones

M. J. González, E. López and R. Vicente, Chem. Commun., 2014, 50, 5379 DOI: 10.1039/C3CC47481J

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