Issue 40, 2014

Can non-polar hydrogen atoms accept hydrogen bonds?

Abstract

We examine an unusual case where a neutral hydrogen atom acts as a hydrogen-bond acceptor. The association constant between trihexylsilane and perfluoro-tert-butanol was measured as ∼0.8 M−1 in cyclohexane. Computations and experimental NMR data are consistent with a weak, but favourable Si–H⋯HO interaction.

Graphical abstract: Can non-polar hydrogen atoms accept hydrogen bonds?

Supplementary files

Article information

Article type
Communication
Submitted
07 Aug. 2013
Accepted
20 Sept. 2013
First published
22 Okt. 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 5212-5214

Can non-polar hydrogen atoms accept hydrogen bonds?

L. Yang, T. A. Hubbard and S. L. Cockroft, Chem. Commun., 2014, 50, 5212 DOI: 10.1039/C3CC46048G

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