Issue 45, 2013

A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Abstract

Solvothermal reaction of a dendritic hexacarboxylic acid with Tb(NO3)3·6H2O afforded a mesoporous lanthanide–organic framework (UTSA-61) whose single-crystal X-ray structure was characterized to have octahedral cages of 2.4 nm in diameter. This mesoporous MOF not only exhibits novel hey topology, but also maintains permanent porosity as shown in its N2, H2, CO2 and CH4 gas sorption isotherms.

Graphical abstract: A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Supplementary files

Article information

Article type
Communication
Submitted
08 Jūn. 2013
Accepted
29 Jūl. 2013
First published
31 Jūl. 2013

CrystEngComm, 2013,15, 9328-9331

A mesoporous lanthanide–organic framework constructed from a dendritic hexacarboxylate with cages of 2.4 nm

Y. He, H. Furukawa, C. Wu, M. O'Keeffe and B. Chen, CrystEngComm, 2013, 15, 9328 DOI: 10.1039/C3CE41062E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements