Issue 39, 2013
From the journal:

Chemical Communications

Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand†‡

Takashi Okubo,*ab   Haruho Anma,a   Naoya Tanaka,a   Kento Himoto,a   Shu Seki,c   Akinori Saeki,cb   Masahiko Maekawaa  and  Takayoshi Kuroda-Sowaa  

* Corresponding authors

a Kinki University, 3-4-1 Kowakae, Higashi-Osaka-shi, Osaka 577-8502, Japan
E-mail: okubo_t@chem.kindai.ac.jp
Fax: +81-6-6723-2721
Tel: +81-6-6730-5880 (ex. 4117)

b PRESTO, Japan Science and Technology Agency (JST), Japan

c Department of Applied Chemistry, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan

Abstract

A novel mixed-valence Cu(I)–Cu(II) coordination polymer with an infinite two-dimensional structure, [Cu3ICuIIBr3(3,5-Dmpip-dtc)2]n (3,5-Dmpip-dtc− = 3,5-dimethylpiperidine dithiocarbamate), was prepared, and its structure was characterized by X-ray diffraction. It shows semiconducting behavior with a relatively small activation energy and high carrier mobility, which were investigated using impedance spectroscopy and flash photolysis time-resolved microwave conductivity measurements, respectively.

Graphical abstract: Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand

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Article information

DOI
https://doi.org/10.1039/C2CC37137E
Article type
Communication
Submitted
01 Okt. 2012
Accepted
10 Dec. 2012
First published
19 Dec. 2012

Chem. Commun., 2013,49, 4316-4318

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Crystal structure and carrier transport properties of a new semiconducting 2D coordination polymer with a 3,5-dimethylpiperidine dithiocarbamate ligand

T. Okubo, H. Anma, N. Tanaka, K. Himoto, S. Seki, A. Saeki, M. Maekawa and T. Kuroda-Sowa, Chem. Commun., 2013, 49, 4316 DOI: 10.1039/C2CC37137E

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