Issue 23, 2011

Emerging supramolecular synthons: C–H⋯π(chelate) interactions in metal bis(1,1-dithiolates)

Abstract

Crystal structures of transition and main group element 1,1-dithiolates are shown to be partially sustained by C–H⋯π(chelate) interactions. For the planar binary bisdithiocarbamates, C–H⋯π(MS2C) interactions lead to aggregation patterns ranging from a 0-D four molecule aggregate to a 3-D architecture but with the majority of structures featuring 1-D or 2-D supramolecular assemblies.

Graphical abstract: Emerging supramolecular synthons: C–H⋯π(chelate) interactions in metal bis(1,1-dithiolates)

Supplementary files

Article information

Article type
Communication
Submitted
28 Febr. 2011
Accepted
13 Marts 2011
First published
01 Apr. 2011

Chem. Commun., 2011,47, 6623-6625

Emerging supramolecular synthons: C–H⋯π(chelate) interactions in metal bis(1,1-dithiolates)

E. R. T. Tiekink and J. Zukerman-Schpector, Chem. Commun., 2011, 47, 6623 DOI: 10.1039/C1CC11173F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements