Issue 21, 2024

Recent advances in the fabrication of organic solvent nanofiltration membranes using covalent/metal organic frameworks

Abstract

Organic solvent nanofiltration (OSN) has evolved as a vital technological frontier with paramount significance in the separation and purification of organic solvents. Its implication is particularly prominent in industries such as pharmaceuticals, petrochemicals, and environmental remediation. This comprehensive review, meticulously navigates through the current state of research in OSN membranes, unveiling both the critical challenges and promising opportunities that beckon further exploration. The central focus of this review is on the unique utilization of covalent organic frameworks (COFs) and metal–organic frameworks (MOFs) in OSN membrane design, leveraging their distinctive structural attributes—tunable porosity, robust chemical stability, and molecular sieving capabilities. These qualities position them as exceptional candidates for crafting membranes tailored to the intricacies of organic solvent environments. Our investigation extends into the fundamental principles that render COFs and MOFs adept in OSN applications, dissecting their varied fabrication methods while offering insights into the advantages and limitations of each. Moreover, we address environmental and sustainability considerations in the use of COF and MOF-based OSN membranes. Furthermore, we meticulously present the latest advancements and innovations in this burgeoning field, charting a course toward potential future directions and emerging research areas. By underscoring the challenges awaiting exploration, this review not only provides a panoramic view of the current OSN landscape but also lays the groundwork for the evolution of efficient and sustainable OSN technologies, specifically harnessing the unique attributes of COFs and MOFs.

Graphical abstract: Recent advances in the fabrication of organic solvent nanofiltration membranes using covalent/metal organic frameworks

Article information

Article type
Feature Article
Submitted
12 Dec. 2023
Accepted
12 Febr. 2024
First published
19 Febr. 2024

Chem. Commun., 2024,60, 2865-2886

Recent advances in the fabrication of organic solvent nanofiltration membranes using covalent/metal organic frameworks

E. Azadi, N. Singh, M. Dinari and J. S. Kim, Chem. Commun., 2024, 60, 2865 DOI: 10.1039/D3CC06057H

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