Issue 6, 2023

Chemical fuel-driven gelation with dissipative assembly-induced emission

Abstract

Fuel-driven dissipative self-assembly is ubiquitous in living systems, such as the formation of microtubules and mitotic spindles. The study of out-of-equilibrium materials is of great significance for the development of life-like processes in chemistry. Herein, we designed and constructed a dissipative self-assembly system based on the hydrophilic multiple-carboxylate-anion molecules G1 and G2, by using dimethyl sulfate (DMS) as the chemical fuel. The mixed aqueous solution of G1 and G2 can be rapidly transformed into a hybrid hydrogel upon the addition of DMS, and then it slowly changed back into a sol solution. Intriguingly, the dissipative self-assembly process can simultaneously induce a strong fluorescence emission enhancement owing to the rigidification of the matrix.

Graphical abstract: Chemical fuel-driven gelation with dissipative assembly-induced emission

Supplementary files

Article information

Article type
Research Article
Submitted
27 Nov. 2022
Accepted
14 Janv. 2023
First published
18 Janv. 2023

Org. Chem. Front., 2023,10, 1380-1385

Chemical fuel-driven gelation with dissipative assembly-induced emission

M. Cheng, D. Chen, L. Zhang, T. Xiao, J. Jiang and L. Wang, Org. Chem. Front., 2023, 10, 1380 DOI: 10.1039/D2QO01888H

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